Interaction of graphite and its compounds with ferrocene under microwave synthesis
https://doi.org/10.34680/2076-8052.2021.4(125).24-28
Abstract
The paper deals with the synthesis of carbon nanostructures under microwave treatment of mixtures of ferrocene with solid carbon materials as microwave receptors that contribute to the maximum conversion of the energy of microwave electromagnetic radiation into the thermal factor of reaction process. Graphite, graphite oxide and thermally expanded graphite have been studied as effective microwave receptors. It is shown that microwave treatment of a mixture of graphite with ferrocene is accompanied by the formation of multi-walled carbon nanotubes of “match” morphology with a diameter of 60-70 nm in the form of intertwined ropes. When oxide graphite or thermally expanded graphite are used in the process, mainly three-dimensional nanostructures of grapheme / carbon nanotubes and the low-layer packets of micron-sized graphene planes are formed. In the case of thermally expanded graphite, nanostructures of toroidal morphology were also recorded among the synthesized products. The data of electron microscopy (TEM, SEM) of the obtained nanoobjects are presented.
About the Authors
A. N. Zaritovsky
Институт физико-органической химии и углехимии им. Л.М. Литвиненко
Russian Federation
Russian Federation
E. N. Kotenko
Институт физико-органической химии и углехимии им. Л.М. Литвиненко
Russian Federation
Russian Federation
Ya. V. Demko
Институт физико-органической химии и углехимии им. Л.М. Литвиненко
Russian Federation
Russian Federation
T. A. Zaritovskaya
Институт физико-органической химии и углехимии им. Л.М. Литвиненко
Russian Federation
Russian Federation
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Review
For citations:
Zaritovsky A.N., Kotenko E.N., Demko Ya.V., Zaritovskaya T.A. Interaction of graphite and its compounds with ferrocene under microwave synthesis. Title in english. 2021;(4(125)):24-28. (In Russ.) https://doi.org/10.34680/2076-8052.2021.4(125).24-28
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